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71.
For many basins, identifying changes to water quality over time and understanding current hydrologic processes are hindered by fragmented and discontinuous water‐quality and hydrology data. In the coal mined region of the New River basin and Indian Fork sub‐basin, muted and pronounced changes, respectively, to concentration–discharge (C–Q) relationships were identified using linear regression on log‐transformed historical (1970s–1980s) and recent (2000s) water‐quality and streamflow data. Changes to C–Q relationships were related to coal mining histories and shifts in land use. Hysteresis plots of individual storms from 2007 (New River) and the fall of 2009 (Indian Fork) were used to understand current hydrologic processes in the basins. In the New River, storm magnitude was found to be closely related to the reversal of loop rotation in hysteresis plots; a peak‐flow threshold of 25 cubic meters per second (m3/s) segregates hysteresis patterns into clockwise and counterclockwise rotational groups. Small storms with peak flow less than 25 m3/s often resulted in dilution of constituent concentrations in headwater tributaries like Indian Fork and concentration of constituents downstream in the mainstem of the New River. Conceptual two or three component mixing models for the basins were used to infer the influence of water derived from spoil material on water quality. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   
72.
A new load surface based approach to the reliability analysis of caisson-type breakwater is proposed. Uncertainties of the horizontal and vertical wave loads acting on breakwater are considered by using the so-called load surfaces, which can be estimated as functions of wave height, water level, and so on. Then, the first-order reliability method(FORM) can be applied to determine the probability of failure under the wave action. In this way, the reliability analysis of breakwaters with uncertainties both in wave height and in water level is possible. Moreover, the uncertainty in wave breaking can be taken into account by considering a random variable for wave height ratio which relates the significant wave height to the maximum wave height. The proposed approach is applied numerically to the reliability analysis of caisson breakwater under wave attack that may undergo partial or full wave breaking.  相似文献   
73.
Subsurface flow and heat transport near Freienbrink, NE Germany, was simulated in order to study groundwater–surface water exchange between a floodplains aquifer and a section of the lowland River Spree and an adjacent oxbow. Groundwater exfiltration was the dominant process, and only fast surface water level rises resulted in temporary infiltration into the aquifer. The main groundwater flow paths are identified based on a 3D groundwater flow model. To estimate mass fluxes across the aquifer–surface water interfaces, a 2D flow and heat transport modelling approach along a transect of 12 piezometers was performed. Results of steady‐state and transient water level simulations show an overall high accuracy with a Spearman coefficient ρ = 0.9996 and root mean square error (RMSE) = 0.008 m. Based on small groundwater flow velocities of about 10?7 to 10?6 ms?1, mean groundwater exfiltration rates of 233 l m?2 d?1 are calculated. Short periods of surface water infiltration into the aquifer do not exceed 10 days, and the infiltration rates are in the same range. The heat transport was modelled with slightly less accuracy (ρ = 0.8359 and RMSE = 0.34 °C). In contrast to the predominant groundwater exfiltration, surface water temperatures determine the calculated temperatures in the upper aquifer below both surface water bodies down to 10 m during the whole simulation period. These findings emphasize prevailing of heat conduction over advection in the upper aquifer zones, which seems to be typical for lowland streams with sandy aquifer materials and low hydraulic gradients. Moreover, this study shows the potential of coupled numerical flow and heat transport modelling to understand groundwater–surface water exchange processes in detail. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   
74.
Contact aureoles of the anorthositic to granitic plutons of the Mesoproterozoic Nain Plutonic Suite (NPS), Labrador, are particularly well developed in the Palaeoproterozoic granulite facies, metasedimentary, Tasiuyak gneiss. Granulite facies regional metamorphism (MR), c. 1860 Ma, led to biotite dehydration melting of the paragneiss and melt migration, leaving behind biotite‐poor, garnet–sillimanite‐bearing quartzofeldspathic rocks. Subsequently, Tasiuyak gneiss within a c. 1320 Ma contact aureole of the NPS was statically subjected to lower pressure, but higher temperature conditions (MC), leading to a second partial melting event, and the generation of complex mineral assemblages and microstructures, which were controlled to a large extent by the textures of the MR assemblage. This control is clearly seen in scanning electron microscopic images of thin sections and is further supported by phase equilibria modelling. Samples collected within the contact aureole near Anaktalik Brook, west of Nain, Labrador, mainly consist of spinel–cordierite and orthopyroxene–cordierite (or plagioclase) pseudomorphs after MR sillimanite and garnet, respectively, within a quartzofeldspathic matrix. In addition, some samples contain fine‐grained intergrowths of K‐feldspar–quartz–cordierite–orthopyroxene inferred to be pseudomorphs after osumulite. Microstructural evidence of the former melt includes (i) coarse‐grained K‐feldspar–quartz–cordierite–orthopyroxene domains that locally cut the rock fabric and are inferred to represent neosome; (ii) very fine‐ to medium‐grained cordierite–quartz intergrowths interpreted to have formed by a reaction involving dissolution of biotite and feldspar in melt; and (iii) fine‐scale interstitial pools or micro‐cracks filled by feldspar interpreted to have crystallized from melt. Ultrahigh temperature (UHT) conditions during contact metamorphism are supported by (i) solidus temperatures >900 °C estimated for all samples, coupled with extensive textural evidence for contact‐related partial melting; (ii) the inferred (former) presence of osumilite; and (iii) titanium‐in‐quartz thermometry indicating temperatures within error of 900 °C. The UHT environment in which these unusual textures and minerals were developed was likely a consequence of the superposition of more than one contact metamorphic event upon the already relatively anhydrous Tasiuyak gneiss.  相似文献   
75.
“一带一路”倡议是新时期中国为加强对外开放提出的全球化合作倡议,资源环境的优化配置对全球化发展意义重大。气温作为重要的基础数据和输入要素,对其进行空间化处理是实现大尺度区域资源环境优化配置的前提。本文基于地理信息技术(GIS),运用距离平方反比法(IDS)、协同克里格法(CK)、回归距离平方反比法(RIDS)和回归协同克里格法(RCK),对“一带一路”地区1980—2017年的2679个气象站点的月平均气温和年平均气温数据进行插值,获得了“一带一路”地区10 km分辨率的气温空间分布数据。交叉验证结果表明:① IDS、CK、RIDS和RCK插值法在整体上均较好地展示了“一带一路”地区气温的地理空间分布规律,4种插值方法的月均气温的均方根误差分别在1.93~2.43、1.78~2.14、1.31~2.23和1.23~1.92 ℃之间;年均气温的均方根误差分别为1.94、1.83、1.37和1.27 ℃;② 在“一带一路”地区,加入协变量分析的CK插值精度整体优于IDS,并且削弱了IDS的极值现象;③ RIDS和RCK对年均气温的插值精度分别较IDS和CK提高了29.4%和30.6%,表明加入地理要素并进行残差修正的插值精度得到了进一步提高。总体来看,RCK插值法对气温数据的插值精度最高,可以考虑将此方法作为“一带一路”地区温度等气象要素的插值方法。  相似文献   
76.
热岩石圈厚度是研究盆地的构造演化和板块动力学的重要参数,本文通过实测数据构建地壳分层模型,根据热传导的基本原理,计算了冀中坳陷中部的Moho面温度以及热岩石圈厚度,并探讨其地热学意义。结果表明:冀中坳陷中部的Moho面温度分布在500~600℃,西南侧整体温度较东北部高,热岩石圈厚度介于102~122km,其平面展布特征与华北克拉通热岩石圈厚度西厚东薄的特征相吻合,为华北克拉通受太平洋板块西向俯冲导致东部遭受破坏提供了依据,并且较薄的岩石圈使热流更易传导到地壳浅部,成为了该地区热异常的成因背景。  相似文献   
77.
The majority of coalbed methane(CBM) in coal reservoirs is in adsorption states in coal matrix pores. To reveal the adsorption behavior of bituminous coal under high-temperature and high-pressure conditions and to discuss the microscopic control mechanism affecting the adsorption characteristics, isothermal adsorption experiments under hightemperature and high-pressure conditions, low-temperature liquid nitrogen adsorption-desorption experiments and CO2 adsorption experiments were performed on coal samples. Results show that the adsorption capacity of coal is comprehensively controlled by the maximum vitrinite reflectance(Ro, max), as well as temperature and pressure conditions. As the vitrinite reflectance increases, the adsorption capacity of coal increases. At low pressures, the pressure has a significant effect on the positive effect of adsorption, but the effect of temperature is relatively weak. As the pressure increases, the effect of temperature on the negative effect of adsorption gradually becomes apparent, and the influence of pressure gradually decreases. Considering pore volumes of pores with diameters of 1.7-100 nm, the peak volume of pores with diameters 10-100 nm is higher than that from pores with diameters 1.7-10 nm, especially for pores with diameters of 40-60 nm, indicating that pores with diameters of 10-100 nm are the main contributors to the pore volume. The pore specific surface area shows multiple peaks, and the peak value appears for pore diameters of 2-3 nm, indicating that this pore diameter is the main contributor to the specific surface area. For pore diameters of 0.489-1.083 nm, the pore size distribution is bimodal, with peak values at 0.56-0.62 nm and 0.82-0.88 nm. The adsorption capability of the coal reservoir depends on the development degree of the supermicroporous specific surface area, because the supermicroporous pores are the main contributors to the specific pore area. Additionally, the adsorption space increases as the adsorption equilibrium pressure increases. Under the same pressure, as the maximum vitrinite reflectance increases, the adsorption space increases. In addition, the cumulative reduction in the surface free energy increases as the maximum vitrinite reflectance increases. Furthermore, as the pressure increases, the surface free energy of each pressure point gradually decreases, indicating that as the pressure increases, it is increasingly difficult to adsorb methane molecules.  相似文献   
78.
榍石LA-SF-ICP-MS U-Pb定年及对结晶和封闭温度的指示   总被引:1,自引:0,他引:1  
榍石富含U、Th,贫Pb,是U-Pb定年的理想矿物之一。本文采用激光剥蚀-高分辨等离子体质谱建立榍石U-Pb定年方法,采用25~30μm激光斑束,准确测定榍石U-Pb标准样品BLR-1(~1048Ma)、OLT-1(~1014Ma)和Pakistan(~21.4Ma),以及年轻榍石样品(<100Ma)U-Pb年龄,提高了检测准确性和空间分辨率。综合对比共生锆石和榍石U-Pb年龄、榍石颗粒微量元素和U-Pb年龄环带及不同成分岩浆岩(SiO2含量48.1%~77.0%)中岩浆榍石的结晶温度,结果表明:岩浆演化过程中,榍石具有宽泛的结晶温度(600~900℃,峰值~750℃),主要集中于岩浆演化中晚期结晶,榍石U-Pb同位素封闭温度接近或略低于锆石,因此同一岩浆体系中锆石与榍石的年龄差异可能反映了该熔体较晚达到榍石饱和,而非熔体热演化历史或封闭温度信息。  相似文献   
79.
青藏高原东北缘是青藏高原隆升的前缘地带,其构造变形特征一直是研究的热点。前人在该区域进行过面波成像研究,但不同结果存在较明显的差异,可能与不同成像方法的分辨率有关,此次研究分别使用基于射线的方法和基于程函方程的方法进行了瑞利波相速度成像。笔者对比了20 s、30 s和60 s的成像结果,两种方法的结果表现出相似的速度特征。总体的速度特征与研究区域的主要构造单元分布相吻合,青藏高原东北缘表现出低速异常,鄂尔多斯块体表现出高速异常。在银川河套地堑,基于程函方程的成像在20 s和30 s得到更明显的低速异常,低速异常体的分布与地堑的轮廓吻合更好,说明基于程函方程的方法对数据利用更充分。  相似文献   
80.
利用1989、2003、2018年的Landsat影像对安顺市西秀区的地表温度进行反演,分析研究区在30年发展中的热岛时空变化及其成因。使用基于影像的反演算法,结合分类回归树算法进行地表温度的反演,用气象站数据对反演结果进行精度验证,并建立缓冲区对研究区进行相关性分析等定量分析。结果表明:研究区受喀斯特地貌的影响,除主城区外,郊区也存在大量高温区;近30年研究区热效应与不透水面、绿地的面积有极显著相关;1989-2003年研究区城市热岛面积随城市扩张逐渐增大,但2018年主城区城市热岛现象几乎完全消失,排除气象因素和城市形态因子影响的可能后,发现这与安顺市城市绿化的大力进行有密切关系。  相似文献   
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